Mass Spectrometric Liquid Chromatography And The Matrix Effect
The matrix effect is a common problem encountered during liquid chromatography mass spectrometry. The matrix effect arises from the fact that in order to achieve good peak elution, the separation of an analyte from other compounds in the slurry must be such that it does not cause any interaction between the analyte and its resulting ion signal. An alternative approach is to purify your sample prior to analysis by preparative chromatography.
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